The municipality of Rapu - Rapu comprises 3 islands namely: Batan, Rapu - Rapu and Guinanayan. The Centro which is Poblacion is in Rapu - Rapu island. The municipality is composed of a total of 34 barangays:
| Malobago | Guadalupe | Carogcog |
| Poblacion | Binosawan | Tinopan |
| Batan | Mancao | Galicia |
| Bohatan | Nagcalsot | Calanaga |
| San Ramon | Liguan | Gaba |
| Sagrada | Tinocawan | Villa Hermosa |
| Masaga | Manila | Caracaran |
| Lagundi | Bogtong | Dapdap |
| Bagaobawan | Mananao | Buenavista |
| Viga | Linao | Pagcolbon |
| Morocborocan | Sta. Barbara | Bilbao |
| Hamorawon |
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| Carogcog, Rapu - Rapu, Albay |
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| View of Batan Island from Brgy. Malobago |
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| Liguan, Rapu - Rapu, Albay |
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| Brgy. Galicica, Batan Island |
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